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Low-cost production of nanocellulose from diverse lignocellulosic feedstocks has become an important topic for developing sustainable nanomaterials. The available feedstocks include both woody and non-woody plants, where the latter are relatively underutilized. Interestingly, the porous structure and low lignin content in most non-woody plants, such as agricultural residues and natural fibers, also makes them ideal sources for lower energy nanocellulose production using simpler methods than those required to process woody plants. To enhance the goal of circularity, this review first provides an overview of the nanocellulose conversion from cellulose and then comprehensively discusses the use of non-woody feedstocks for nanocellulose production. Specifically, the availability of suitable non-woody feedstocks and the use of low-cost processes for pulping and cellulose oxidation treatments, including alkaline, solvent pulping, and nitrogen-oxidation treatments, are discussed. The information in this review can lead to new opportunities to achieve greater sustainability in biobased economies. Additionally, demonstrations of nanocellulose-based water purification technologies using agricultural residues derived remediation materials are highlighted at the end of this review.more » « less
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Joshi, Ritika; Sebat, Nilay; Chi, Kai; Khan, Madani; Johnson, Ken I.; Alhamzani, Abdulrahman G.; Habib, M. A.; Lindstrom, Tom; Hsiao, Benjamin S. (, Membranes)Ultrafiltration (UF) is a common technique used in wastewater treatments. However, the issue of membrane fouling in UF can greatly hinder the effectiveness of the treatments. This study demonstrated a low-fouling composite cellulose membrane system based on microfibrillated cellulose (MFC) and silica nanoparticle additives. The incorporation of ‘non-spherical’ silica nanoparticles was found to exhibit better structural integration in the membrane (i.e., minimal aggregation of silica nanoparticles in the membrane scaffold) as compared to spherical silica. The resulting composite membranes were tested for UF using local wastewater, where the best-performing membrane exhibited higher permeation flux than commercial polyvinylidene difluoride (PVDF) and polyether sulfone (PES) membranes while maintaining a high separation efficiency (~99.6%) and good flux recovery ratio (>90%). The analysis of the fouling behavior using different models suggested that the processes of cake layer formation and pore-constriction were probably two dominant fouling mechanisms, likely due to the presence of humic substances in wastewater. The demonstrated cellulose composite membrane system showed low-fouling and high restoration capability by a simple hydraulic cleaning method due to the super hydrophilic nature of the cellulose scaffold containing silica nanoparticles.more » « less
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